Eevee is a Daily Pokemon in the Trophy Garden. Mr. Backlot tells you what the daily Pokemon is when you talk to him (also, yesterday's Pokemon is in there as well. They're there for two days before they migrate again.) You can catch Eevee here, but the encounter rate is only 5% so you'll be in there for a while.
If you really, really want your Eevee, and you have a lot of time on your hands, here's how you catch Eevee in the Trophy Garden:
If you find yourself cycling through the same Pokemon, Eevee might be yesterday's Pokemon.
He's going to be between level 16 and 18 so either equip an appropriately leveled Pokemon or a Pokemon with False Swipe (like Sneasel) and bring lots of Balls to catch him!
Good luck! He's rare, but worth it!
OR IF U HAVE A JOLTEON, VAPOREON, ETC. U CAN ALSO MATE THT W/ DITTO
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