Primary and secondary alcohols are more reactive than tertiary alcohols due to their structure, which allows for easier protonation and subsequent reaction with electrophiles. Primary and secondary alcohols have fewer steric hindrances compared to tertiary alcohols, making it easier for nucleophiles to approach and react with the hydroxyl group. Additionally, the carbon in tertiary alcohols is more stable and less likely to participate in reactions, such as dehydration or oxidation, compared to the more reactive primary and secondary alcohols.
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