Why 8086 has 6 byte que?

Because that's how Intel designed it.

They chose a 6 byte queue in the 8086 in order to optimize speed versus latency of the execution unit versus the bus interface unit. The decision for 6 bytes, as compared to 4 or 8 or some other number was a cost tradeoff and a recognition of the average mix of instruction execution cycle times in a typical processing thread.