You can start the Birth Control pill at any time in your cycle. If you are set on starting on a Sunday, then you'll need to use a back up method of birth control for a week, unless it's been five days or fewer since you started your period.
Traditionally, women in the US started the birth control pill on Sunday. This has an obvious disadvantage - your health care provider's office is closed on Sunday, and many women start their pill late when they notice too late that they're out of pills. Do yourself a favor and consider starting on a weekday, as they do in most other countries.
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