LatiOS ways a few more pounds making it easier to catch with the Heavy Ball. Also, LatiOS has 20 more Base Sp. Attack than Latias (130 in total), whereas Latias has 20 more Base Sp. Defense than LatiOS(130 in Total)
A comparison from Psypokes:
Latias
HP80ATK80DEF90SA110SD130SPD110
LatiOS
HP80ATK90DEF80SA130SD110SPD110
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