Opportunistic is defined as:
Taking immediate advantage, often unethically, of any circumstance of possible benefit.
(http:/www.thefreedictionary.com/opportunistic)
If we take the direct opposite of it, it will be:
"inexpedient"
(http:/www.opposite-Word.com/o/opportunistic)
which is defined as:
not suitable, advisable, or judicious
(http:/www.thefreedictionary.com/inexpedient)
I think this pair of Words doesn't really show the opposite meaning.
My opinion is, if we see 'opportunistic' as self-centered behavior of someone, which then displace this Word closer to
'egoistic' : One devoted to one's own interests and advancement; an egocentric person.
(http:/www.thefreedictionary.com/egoistic)
maybe the most suitable opposite Word of it would be:
altruistic(http:/www.opposite-Word.com/default.asp)
which is: (altruism) Unselfish concern for the welfare of others; selflessness.
(http:/www.thefreedictionary.com/altruistic)
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