There is not collective noun for the Word 'loaf'. A collective noun is a Word for a group of things; the noun loaf is a singular, one loaf.
The plural noun is 'loaves'. Some collective nouns for loaves are a batch of loaves or a stack of loaves. Other collective nouns for loaves would be a Word suitable for the context of the loaves; for example a basket of loaves, a shelf of loaves, a case of loaves, etc.
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