Primary, secondary, and tertiary alcohols can be distinguished based on the number of carbon atoms bonded to the carbon atom that carries the hydroxyl (-OH) group. In primary alcohols, the -OH group is attached to a carbon that is bonded to only one other carbon atom. In secondary alcohols, the -OH group is connected to a carbon bonded to two other carbons, while in tertiary alcohols, the -OH group is on a carbon bonded to three other carbons. This can be confirmed using chemical tests, such as oxidation reactions, where primary alcohols oxidize to aldehydes, secondary alcohols to ketones, and tertiary alcohols do not oxidize easily.
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