This site explains the changes, the excerpt is a small explanation:
The item is heated to temperatures up to 1170oC, during which time the clay undergoes
some chemical changes and the silica and feldspar undergo physical changes. The
reactions of the clay can be summarised as follows:
6Al2Si2O5(OH)4 ? 6Al2Si2O7 ? 3Al4Si3O12 ? 2Al6Si2O13
kaolinite metakaolinite silicon spinel mullite
Silica and water (from the crystal lattice) are also expelled during firing, resulting in a
further 5 - 7% volume reduction. This silica mixes with the silica already present and
melts to form a glass. It is this glass, which also includes metallic ions from the
feldspar, that makes the ceramic item non-porous and water-tight.
* The site: http://www.nzic.org.nz/ChemProcesses/inorganic/9C.pdf
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