There's a product called Concrete Rust Remover that's available from "The Rust Store" that works wonders on removing rust stains from driveways, sidewalks, etc. I had previously tried several other products with no luck, but then found this product online. It's available at http://www.theruststore.com.
I have used LimeAway with fair success on small rust stains on concrete. Just squirt it on the stain and let it set a bit, then scrub a bit and rinse. It may take more than one application but the results were pretty good for me.
Another product we have had great success with is F9 Cleaner from Front9Restoration.com. It removed 100% of our driveway rust.
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