Sugars starches and some fibers are classified as?

Resistant starch (which is starch that is resistant to digestion) falls, both by definition and functionality, in the much broader category of dietary fiber, which is defined as is the indigestible portion of food derived from plants. So your question sounds like “what is the difference between Apples and fruits?” Difficult to answer. Chemically, dietary fiber consists of non-starch polysaccharides such as arabinoxylans, cellulose, and many other plant components such as resistant dextrins, inulin, lignin, chitins, pectins, beta-glucans, and oligosaccharides. They have many differences with the resistant starch and between them.

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