Solid silver is denser.
Remember in a solid the atoms are closely packed and in a regular order.
When it is a liquid the atoms are less closely packed an in an irregular order.
Since liquid atoms are less closely packed, the same number of atoms occupy a larger space/volume.
Since they occupy a larger volume for the same number then liquids arr less dense.
Density = mass/ volume.
Solid ; Using 1 gram (Silver) occupies say 0.25 cm^(3) of space
Liquid ; using 1 gram(silver) occupies say 0.255 cm^(3) of space.
Hence
Density (Solid) =- 1/ 0.25 = 4 g/cm^(3)
Density (Liquid) = 1 / 0.255 = 3.91,,, g/cm^(3)
These are fictitious figures , just given to demonstrate.
Also , remember when a mass gains energy it changes from solid to liquid and EXPANDS(Greater volume/space).
So a block of solid silver , when placed in liquid silver will sink, because it is more dense.
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