The starter relay switch on a 2005 Chrysler 300C with a 5.7L engine is located in the Power Distribution Center (PDC), which is situated in the engine compartment near the battery. To access it, you'll need to open the PDC cover, and the relay is typically marked on the cover diagram. It's important to ensure the vehicle is turned off and the battery is disconnected before attempting to replace or inspect the relay.
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