If you wanted to speak of brotherly/sisterly sentiments in French, the adjective "fraternel / fraternelle" would be used. They come from the Latin Word fratria used to speak of siblings (boys and girls alike).
Technically, a French adjective related to the Word "soeur" (sister) is the Word "sororel" which shares the same roots as "sister" or "sorority". Absolutely nobody will understand it.
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