It is not a proper Word, but traditionally when it is used, it is a contraction for am not. Contractions use an apostrophe.
Example:
I am not going into that dark cave.
I ain't going into that dark cave.
In writing, it should only be used as a slang. For instance, it would help add traits to a character in a novel. However, it should never be used in formal or business writing.
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