Which case clarified that the constitutional overriders all other laws?

The case that clarified the supremacy of the Constitution over all other laws is Marbury v. Madison (1803). In this landmark decision, Chief Justice John Marshall established the principle of judicial review, asserting that it is the duty of the judiciary to declare what the law is. This ruling reinforced that any law conflicting with the Constitution is void, thereby affirming the Constitution as the supreme law of the land.