Yes, you can substitute bicarbonate of soda (baking soda) for baking powder, but you'll need to adjust the recipe. Baking powder contains both an acid and a base, while baking soda is purely a base. To use baking soda instead, you should add an acid (like vinegar or lemon juice) to the recipe to activate it, typically about 1/2 teaspoon of acid for every 1/4 teaspoon of baking soda used. Keep in mind that you'll need to use less baking soda than the amount of baking powder called for.
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