Magnesium oxide is a base because it can produce hydroxide ions in solution. (The definition of a base by Bronsted-Lowry is that it is a proton (that is, a hydrogen ion, because hydrogen ions have no neutron and have lost their electron, so they are just left with a proton) acceptor.
MgO+H2O ---- Mg+2OH
Therefore, it produces hydroxide ions in solution.
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