In a covalent bond, when one atom attracts the shared electrons more strongly than the other, it creates a polar covalent bond. This occurs due to differences in electronegativity between the two atoms, where the atom with higher electronegativity pulls the shared electrons closer, resulting in a partial negative charge on that atom and a partial positive charge on the other. This uneven distribution of electron density leads to molecular polarity, influencing the molecule's physical properties and reactivity.
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