The hardening of mortar is primarily due to the hydration of cement, which involves a chemical reaction between water and the compounds in cement, primarily tricalcium silicate (C3S) and dicalcium silicate (C2S). When water is added, these compounds react to form calcium silicate hydrate (C-S-H) and calcium hydroxide (Ca(OH)2), which contribute to the strength and stability of the mortar. The simplified reaction for the hydration of tricalcium silicate can be represented as:
[ 2 \text{C}_3\text{S} + 6 \text{H} \rightarrow 3 \text{C-S-H} + 3 \text{Ca(OH)}_2 ]
This process continues over time, leading to the hardening of the mortar.
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