Potassium chloride is an ionic compound, composed of positive potassium ions and negative chloride ions. When it dissolves in water, the ions separate and become surrounded by water molecules. Water is a covalent compound, but it is polar, which means that one end (the oxygen) is a little bit negative, and the other is a little bit positive. The slightly negative ends are attracted to the positive potassium ions and the slightly positive ends are attracted to the chloride ions. These are electrostatic attractions.
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