Tapioca starch and PVA (polyvinyl acetate) serve different purposes and have distinct properties, so substituting one for the other isn't straightforward. Tapioca starch is a natural thickening agent commonly used in cooking, while PVA is a synthetic polymer often used in adhesives and coatings. If you're looking for a thickening agent, tapioca starch can work, but it won't provide the same adhesive properties as PVA. Always consider the specific application and desired outcome when making substitutions.
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