To calculate the molar mass of a substance using the freezing point depression method, you need to measure the freezing point depression caused by adding a known amount of the substance to a solvent. By using the formula Tf Kf m, where Tf is the freezing point depression, Kf is the cryoscopic constant of the solvent, and m is the molality of the solution, you can then solve for the molality. Finally, by using the formula molality moles of solute / kilograms of solvent, you can determine the moles of solute present and calculate the molar mass of the substance.
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