I have also been confronted with this dilemma. I belive that it is not ideal to workout chest after working out shoulders because your shoulders definetely assist in bench pressing. If your shoulders are sore/weak from the previous days workout, then they could hinder you from putting up as much weight on the bench as normal. Thus your chest will not get a hard workout because your shoulders will give out before your chest. So, I would say work out chest first then shoulders. Although your shoulders might be slightly worn from assisting in the bench pressing, they will still have a lot left to get a good workout in. Also, then they will have been worked out extremely hard.
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