The U.S. requires that you be 21 years old before you are given diplomatic accreditation to the country you are serving in.
Retired Foreign Service Officer
But there's a lot of Youngest Ambassadors the first one is Samantha Smith, she was just 13 years old, she was called the Ambassador for Peace and a Peace Activist between US and the Soviet Union in Cold War, unfortunately she was died in a Plane Crash in 1985.
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