All the tiny air bubbles trapped inside the rice krispies begin bursting when you add the milk, and the small variation in air bubble size's burst with a slightly differant noise, making all the snap crackle n pop sounds you hear.
Em, nice as that sounds I actually think the reason is a little less friendly. I'm pretty sure it's due to the high salt content in Rice Krispies because you get the same reaction when you add cold water to salt
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