The radiation emitted by the Earth peaks around 10 microns, whereas that from the sun peaks under 1 micron. This is why Earth's radiation is referred to as longwave and solar radiation as shortwave, commonly.
All objects emit radiation because all objects have a temperature. In fact, using Wien's Law you can very simply calculate the wavelength, lambda, of maximum emission:
lamda(max) = c/T
where c is a constant (2897) and T is the temperature of the emitting surface in Kelvin.
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