It depends on the solution in which the reaction producing it occurs. A precipitate is formed when a product of a reaction in an aqueous solution is not soluble. Instead of being dissolved in the solution, it 'precipitates' into a solid, which often is suspended in the solution and may cause a color change.
Ba(OH)2 is soluble in water, and therefore will not produce a precipitate in water unless the water is over-saturated or at low temperatures.
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