There are quite a few moves that can make your opponent fall asleep:
Hypnosis - 60% Accuracy - Psychic
Dark Void - 80% Accuracy - Dark
Grasswhistle - 55% Accuracy - Grass
Lovely Kiss - 75% Accuracy - Normal
Sing - 55% Accuracy - Normal
Sleep Powder - 75% Accuracy - Grass
Spore - 100% Accuracy - Grass
Yawn - '--' Accuracy - Normal - (At the end of the turn after using Yawn, the target falls Asleep unless it is switched out.)
Courtesy of Pokemon.Marriland.com
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If you're doing the Pokemon Leaf puzzle on Pokemon.com, then the answer would be spore.
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