The two accessory glands that secrete enzymes to digest starch are the salivary glands and the pancreas. The salivary glands produce saliva, which contains the enzyme amylase that begins starch digestion in the mouth. The pancreas secretes pancreatic amylase into the small intestine, further breaking down starch into simpler sugars for absorption. Together, these glands play a crucial role in carbohydrate digestion.
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