It is often referred to as "smegma." You can view wikipedia's information on smegma by clicking on this link: http://en.wikipedia.org/wiki/Smegma
The discharge from the prepuce is probably normal. There is a thick exudate, referred to as smegma, which is thick yellow to yellow-green in color and is normal. For some reason, it may seem to suddenly accumulate in larger quantities in some dogs.
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