To catch Skitty in Pokémon Black 2, head to Route 4, where it can be found in the tall grass. Skitty has a low encounter rate, so you may need to spend some time searching. Make sure to weaken it in battle without knocking it out, and use Poké Balls to catch it once its health is low. Additionally, using a Pokémon with moves that induce status effects, like Sleep or Paralysis, can increase your chances of a successful capture.
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