The SPF of a sunscreen is a laboratory measure of the effectiveness of sunscreen - the higher the SPF, the more protection a sunscreen offers against UV-B (the ultraviolet radiation that causes sunburn).
The SPF is the amount of UV radiation required to cause sunburn on skin with the sunscreen on, relative to the amount required without the sunscreen.[10] So, wearing a sunscreen with SPF 50, your skin will not burn until it has been exposed to 50 times the amount of solar energy that would normally cause it to burn. The amount of solar energy you are exposed to depends not only on the amount of time you spend in the sun, but also the time of day. This is because, during early morning and late afternoon, the sun's radiation must pass through more of the Earth's atmosphere before it gets to you. In practice, the protection from a particular sunscreen depends on factors such as:
* The skin type of the user.
* The amount applied and frequency of re-application.
* Activities in which one engages (for example, swimming leads to a loss of sunscreen from the skin).
* Amount of sunscreen the skin has absorbed.
The SPF is an imperfect measure of skin damage because invisible damage and skin aging are also caused by ultraviolet type A (UVA, wavelength 320 to 400 nm), which does not cause reddening or pain. Conventional sunscreen blocks very little UVA radiation relative to the nominal SPF; broad spectrum sunscreens are designed to protect against both UVB and UVA.[11][12][13] According to a 2004 study, UVA also causes DNA damage to cells deep within the skin, increasing the risk of malignant melanomas.[14] Even some products labeled "broad-spectrum UVA/UVB protection" do not provide good protection against UVA rays.[15] The best UVA protection is provided by products that contain zinc oxide, avobenzone, and ecamsule. Titanium dioxide probably gives good protection, but does not completely cover the entire UV-A spectrum, as recent research suggests that zinc oxide is superior to titanium dioxide at wavelengths between 340 and 380 nm.[16]
Owing to consumer confusion over the real degree and duration of protection offered, labeling restrictions are in force in several countries. In the EU sunscreen labels can only go up to SPF 50+ (actually indicating a SPF of 60 or higher)[17] while Australia's upper limit is 30+ [18]. The United States does not have mandatory, comprehensive sunscreen standards, although a draft rule has been under development since 1978. In the 2007 draft rule, Food and Drug Administration (FDA) proposed to institute the labelling of SPF 50+ for sunscreens offering more protection. This and other measures were proposed to limit unrealistic claims about the level of protection offered (such as "all day protection").[19]
UV-B sunlight spectrum (on a summer day in the Netherlands), along with the CIE Erythemal action spectrum. The effective spectrum is the product of the former two.
The SPF can be measured by applying sunscreen to the skin of a volunteer and measuring how long it takes before sunburn occurs when exposed to an artificial sunlight source. In the US, such an in vivo test is required by the FDA. It can also be measured in vitro with the help of a specially designed spectrometer. In this case, the actual transmittance of the sunscreen is measured, along with the degradation of the product due to being exposed to sunlight. In this case, the transmittance of the sunscreen must be measured over all wavelengths in the UV-B range (290-320 nm), along with a table of how effective various wavelengths are in causing sunburn (the erythemal action spectrum) and the actual intensity spectrum of sunlight (see the figure). Such in vitro measurements agree very well with in vivo measurements.[20] Numerous methods have been devised for evaluation of UVA and UVB protection The most reliable spectrophotochemical methods eliminate the subjective nature of grading erythema.[21]
The above means that the SPF is not simply the inverse of the transmittance in the UV-B region. If that were true, then applying two layers of SPF 5 sunscreen would be equivalent to SPF 25 (5 times 5). The actual combined SPF is always lower than the square of the single-layer SPF.
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