Most of the value is in the coins rather than the case. The coins were put in the case by someone outside of the Mint, either a collector or a dealer, for display and/or sale.
Despite their interesting history "war nickels" in average condition aren't rare or especially valuable. As of 12/2009 their silver content makes them worth anywhere from $1 in very worn condition to $3-$5 if almost like new.
Uncirculated ones are worth more but you have to know the mint mark letter on the back to determine a specific value.
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