Is it possible that a single man fall in love with a married woman?

I don't know if I would call that a particularly smart idea. At some point, his wife is going to be making a case that she deserves most of his money. If she can point to his infidelity (with you) she can make a stronger case. It is best to wait until the divorce is finalized.

ANSWER:

Could I? wow not sure. It will take a while for me to fall in love to someone, esp. if this man is married but separated. It doesn't matter if this man is separated, he still married. If you fell in love with this man, can you trust him enough, knowing he is separated with his wife. Anyone can fall in love especially if a man (aka- married man) is separated or not, women does it to without a doubt.

I will give you my personal experience, the man I married said so many lies on his profile inside the dating site ( before I found out) he met a married woman as well on a dating site. They dated, seen each others and fell in love to each others while this man was still with me and out children. So you see, a married man don't need to be separated from his wife to fall in love to another person.