Phosphorus trifluoride (PF₃) exhibits dipole-dipole intermolecular forces due to its polar molecular structure. The phosphorus atom is less electronegative than the fluorine atoms, creating a permanent dipole moment. Additionally, London dispersion forces are also present, but they are weaker compared to the dipole-dipole interactions. Overall, the dominant intermolecular force in PF₃ is the dipole-dipole interaction.
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