All of the butanediones have this empirical formula, and there may be other compounds also.
This answer was wrong:
Butadione: first of all: there is only one possible butadion: CH3-C(=O)-C(=O)-CH3 (also named diacetyl)
and secondly butadion is with 6 H atoms (C4H6O2). An alkanon being --C(=O)--, double bonded =O to one 'middle' C atom!.
Right SIX answers or possibilities are (plus 3 enantiomers):
HC(=O)-C'HOH-CH2-CH3 and
HC(=O)-CH2-C'HOH-CH3
CH2OH-C(=O)-CH2-CH3 and
CH3-C(=O)-C'HOH-CH3 and
CH3-C(=O)-CH2-CH2OH
CH3-CH2-CH2-COOH
Improved answer: There are more possibilities:
Esters: Ethyl acetate, methyl propionate, propyl formate and isopropyl formate
Another acid: 2-methylpropanoic acid
Enediols: 3,4-dihydroxy-1-butene (R and S), 1,4-dihydroxy-2-butene (E and Z)
Ether carbonyl compounds: 3-methoxypropanal, 2-methoxypropanal, 2-ethoxyethanal, methoxypropanone
More hydroxy aldehydes: 2-hydroxy-2-methylpropanal, 3-hydroxy-2-methylpropanal
Cyclic compounds: Dioxane, 1,3-dioxacyclohexane, 2-methyl-1,3-dioxacyclopentane, 4-methyl-1,3-dioxacyclopentane (R and S) (and a series of dimethyl-1,3-dioxacyclobutanes if they are viable). There are also cyclic diols such as cyclobutane-1,2-diol (RR, SS and meso) and other cyclobutane isomers, and methylcyclopropanediol isomers. Then there are cyclic and non-cyclic peroxides with O-O bonds.
In short, there are many molecules with the formula: C4H8O2
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