Answer
Mix up a paste of bicarbonate of soda and water. Best to use a paintbrush or something similar to paint the paste onto the grout. Leave for a few hours and then wash off. Grout should be sparkling white. For really stubborn stains, use the same paste on a soft toothbrush and some old fashioned elbow grease.
There is a product from Australia that is a broom on mop off grout cleaner no nasties www.pinkstuff.com.au
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