The kettle of water at 100 degrees Celsius will cool down quicker initially because it is at a higher temperature, and the rate of heat loss is generally greater when there is a larger temperature difference between the water and its surroundings. This phenomenon is described by Newton's Law of Cooling, which states that the rate of heat loss of a body is proportional to the difference in temperature between the body and its environment. However, as the temperatures approach equilibrium, the rate of cooling will slow down for both kettles.
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