What is the relation between flash point and self ignition?

The flash point is the lowest temperature at which a substance can vaporize to form an ignitable mixture in air, while self-ignition, or autoignition, is the temperature at which a substance ignites spontaneously without an external ignition source. Generally, a substance with a low flash point may have a lower self-ignition temperature, making it more hazardous in terms of fire risk. However, the two properties are distinct; a material can have a high flash point yet still have a relatively low self-ignition temperature, depending on its chemical composition and environmental conditions. Understanding both properties is crucial for safe handling and storage of flammable materials.