Egg shells is made up of calcium carbonate. Vinegar aka ethanoic acid is a type of acid. When vinegar come upon contact with the egg shell, the egg shell will corrode making it weak and fragile.
In terms of science, this is what happens:
Calcium carbonate + acid will produce calcium salt + water + carbon dioxide
CaCO3 + CH3COOH -> CH3COOCa + H2O + CO2
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