A molecule adopts a tetrahedral shape when it has four substituents or groups bonded to a central atom, arranged to minimize repulsion according to VSEPR (Valence Shell Electron Pair Repulsion) theory. This typically occurs in molecules where the central atom has four bonding pairs and no lone pairs, such as methane (CH₄). The 109.5° bond angles between the substituents ensure that they are as far apart as possible in three-dimensional space, resulting in a tetrahedral geometry.
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